Coordination Behavior of 3-Ethoxycarbonyltetronic Acid towards Cu(II) and Co(II) Metal Ions

نویسندگان

  • Giorgos Athanasellis
  • Georgia Zahariou
  • Stefanos Kikionis
  • Olga Igglessi-Markopoulou
  • John Markopoulos
چکیده

Tetronic acids, 4-hydroxy-5H-furan-2-ones, constitute a class of heterocyclic compounds with potent biological and pharmacological activity. The beta, beta'-tricarbonyl moiety plays an integral role in biological systems and forms a variety of metal complexes. In this report, we present the complexation reactions of 3-ethoxycarbonyl tetronic acids with acetates and chlorides of Cu(II) and Co(II). These complexes have been studied by means of EPR spectroscopy and magnetic susceptibility measurements. From the obtained results, a preliminary complexation mode of the ligand is proposed.

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عنوان ژورنال:
  • Bioinorganic Chemistry and Applications

دوره 2008  شماره 

صفحات  -

تاریخ انتشار 2008